Radiative charge-transfer lifetime of the excited state of(NaCa)+

Observation of slow charge redistribution preceding excited-state proton transfer.

The photoacid 8-hydroxy-N,N,N',N',N',N'-hexamethylpyrene-1,3,6-trisulfonamide (HPTA) and related compounds are used to investigate the steps involved in excited-state deprotonation in polar solvents using pump-probe spectroscopy and time correlated single photon counting fluorescence spectroscopy. The dynamics show a clear two-step process leading to excited-state proton transfer. The first ste...

Measurement of the excited-state lifetime of a microelectronic circuit.

We demonstrate that a continuously measured microelectronic circuit, the Cooper-pair box measured by a radio-frequency single-electron transistor, approximates a quantum two-level system. We extract the Hamiltonian of the circuit through resonant spectroscopy and measure the excited-state lifetime. The lifetime is more than 10(5) times longer than the inverse transition frequency of the two-lev...

Symmetry-breaking intramolecular charge transfer in the excited state of meso-linked BODIPY dyads.

We report the synthesis and characterization of symmetric BODIPY dyads where the chromophores are attached at the meso position, using either a phenylene bridge or direct linkage. Both molecules undergo symmetry-breaking intramolecular charge transfer in the excited state, and the directly linked dyad serves as a visible-light-absorbing analogue of 9,9'-bianthryl.

Unusual behavior in the first excited state lifetime of catechol

Resonance Raman intensity analysis of the excited state proton transfer dynamics of 2-nitrophenol in the charge-transfer band absorption.

Resonance Raman spectra were obtained for 2-nitrophenol in cyclohexane solution with excitation wavelengths in resonance with the charge-transfer (CT) proton transfer band absorption. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion along more than 15 normal modes: the nominal CCH bend+CC stretch nu(12) (1326 cm(-1)), th...